高氯酸四氨合铜(II)

高氯酸四氨合铜(II)
别名	TACP
识别
CAS号	23667-84-7
性质
化学式	[Cu(NH3)4](ClO4)2
外观	暗蓝色晶体
沸点	222 °C（分解）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

高氯酸四氨合铜(II)是一种无机化合物，化学式为[Cu(NH₃)₄](ClO₄)₂。它可由高氯酸铜和氨水在35 °C反应，并在0 °C结晶得到。^[1]高氯酸六氨合铜(II)在100 °C失去两分子氨，也能得到四氨合物。^[3]它受热快速分解，其分解速率比相应的硝酸盐、亚硝酸盐或碘酸盐快。^[4]它和10-(1-酞嗪基偶氮)-9-菲酚（HL）在三氯甲烷-乙醇中反应，可以得到[Cu₂L₂(H₂O)₄](ClO₄)₂。^[5]

参考文献

^ ^1.0 ^1.1 Ondřej Vodochodský, Martin Künzel, Robert Matyáš, Jinřich Kučera, Jiri Pachman. Tetraamminecopper Perchlorate (TACP): Explosive Properties. Propellants, Explosives, Pyrotechnics. 2021-02, 46 (2): 280–285 [2022-07-27]. ISSN 0721-3115. doi:10.1002/prep.202000131. （原始内容存档于2022-07-27）（英语）.
^ K.C. Patil, V.R.Pai Verneker, S.R. Jain. Role of metal perchlorate ammines on ammonium perchlorate decomposition. Combustion and Flame. 1975-08, 25: 387–388 [2022-07-27]. doi:10.1016/0010-2180(75)90110-8 （英语）.
^ K.C. Patil, V.R. Pai Verneker, S.R. Jain. Metal perchlorate ammines: thermal and infrared studies. Thermochimica Acta. 1976-05, 15 (2): 257–260 [2022-07-27]. doi:10.1016/0040-6031(76)80016-0. （原始内容存档于2018-06-05）（英语）.
^ Gorbunov, V. V.; Shmagin, L. F. Combustion of copper(II) tetrammine salts. Fizika Goreniya i Vzryva, 1972. 8 (4): 523-526. ISSN 0430-6228.
^ R. V. Linko, V. I. Sokol, N. A. Polyanskaya, M. A. Ryabov, P. V. Strashnov, V. V. Davydov, V. S. Sergienko. Crystal and molecular structure and electronic structure of a copper(II) complex with 10-(1-phthalazinylazo)-9-phenanthrol (HL) [Cu2(L)2(H2O)4](ClO4)2. Russian Journal of Inorganic Chemistry. 2013-12, 58 (12): 1457–1464 [2022-07-27]. ISSN 0036-0236. doi:10.1134/S0036023614010094 （英语）.

[prep-1] 1.0 ^1.1 Ondřej Vodochodský, Martin Künzel, Robert Matyáš, Jinřich Kučera, Jiri Pachman. Tetraamminecopper Perchlorate (TACP): Explosive Properties. Propellants, Explosives, Pyrotechnics. 2021-02, 46 (2): 280–285 [2022-07-27]. ISSN 0721-3115. doi:10.1002/prep.202000131. （原始内容存档于2022-07-27）（英语）.

[2] K.C. Patil, V.R.Pai Verneker, S.R. Jain. Role of metal perchlorate ammines on ammonium perchlorate decomposition. Combustion and Flame. 1975-08, 25: 387–388 [2022-07-27]. doi:10.1016/0010-2180(75)90110-8 （英语）.

[3] K.C. Patil, V.R. Pai Verneker, S.R. Jain. Metal perchlorate ammines: thermal and infrared studies. Thermochimica Acta. 1976-05, 15 (2): 257–260 [2022-07-27]. doi:10.1016/0040-6031(76)80016-0. （原始内容存档于2018-06-05）（英语）.

[4] Gorbunov, V. V.; Shmagin, L. F. Combustion of copper(II) tetrammine salts. Fizika Goreniya i Vzryva, 1972. 8 (4): 523-526. ISSN 0430-6228.

[5] R. V. Linko, V. I. Sokol, N. A. Polyanskaya, M. A. Ryabov, P. V. Strashnov, V. V. Davydov, V. S. Sergienko. Crystal and molecular structure and electronic structure of a copper(II) complex with 10-(1-phthalazinylazo)-9-phenanthrol (HL) [Cu2(L)2(H2O)4](ClO4)2. Russian Journal of Inorganic Chemistry. 2013-12, 58 (12): 1457–1464 [2022-07-27]. ISSN 0036-0236. doi:10.1134/S0036023614010094 （英语）.

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