乙酰基六氟锑酸盐
| 乙酰基六氟锑酸盐 | |
|---|---|
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| 识别 | |
| CAS号 | 753-77-5 
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| SMILES |
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| 性质 | |
| 化学式 | C2H3F6OSb |
| 摩尔质量 | 278.8 g·mol−1 |
| 外观 | 无色晶体 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
乙酰基六氟锑酸盐是一种化合物，化学式为CH3COSbF6，它是无色的针状晶体。它可由乙酰氟和五氟化锑在1,1,2-三氟三氯乙烷或二氟二氯甲烷中反应制得，[1]它也可由乙酰氯和无水氟锑酸反应得到。[2]它可以单斜晶系P21/m空间群结晶。[3]
参考文献
- ^ George A. Olah, Stephen J. Kuhn, William S. Tolgyesi and Edward B. Baker. Stable Carbonium Ions. II.1a Oxocarbonium1b (Acylium) Tetrafluoroborates, Hexafluorophosphates, Hexafluoroantimonates and Hexafluoroarsenates. Structure and Chemical Reactivity of Acyl Fluoride: Lewis Acid Fluoride Complexes1c. J. Am. Chem. Soc. 1962, 84, 14, 2733–2740. doi:10.1021/ja00873a019.
- ^ G. A. Olah; J. J. Svoboda (1972). Preparative Carbocation Chemistry. II1. Improved Preparation of Alkyloxocarbenium (Acyl) Hexafluoroantimonate Salts. Synthesis. doi:10.1055/s-1972-21872.
- ^ Milya G. Davlieva, Sergey V. Lindeman, Ivan S. Neretin and Jay K. Kochi. Structural effects of carbon monoxide coordination to carbon centers. π and σ bindings in aliphatic acylversus aromatic aroylcations. New J. Chem., 2004,28, 1568-1574. doi:10.1039/B407654K.