乙酰基六氟銻酸鹽
| 乙酰基六氟銻酸鹽 | |
|---|---|
| |
| 識別 | |
| CAS號 | 753-77-5 
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| SMILES |
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| 性質 | |
| 化學式 | C2H3F6OSb |
| 摩爾質量 | 278.8 g·mol−1 |
| 外觀 | 無色晶體 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
乙酰基六氟銻酸鹽是一種化合物，化學式為CH3COSbF6，它是無色的針狀晶體。它可由乙酰氟和五氟化銻在1,1,2-三氟三氯乙烷或二氟二氯甲烷中反應製得，[1]它也可由乙酰氯和無水氟銻酸反應得到。[2]它可以單斜晶系P21/m空間群結晶。[3]
參考文獻
- ^ George A. Olah, Stephen J. Kuhn, William S. Tolgyesi and Edward B. Baker. Stable Carbonium Ions. II.1a Oxocarbonium1b (Acylium) Tetrafluoroborates, Hexafluorophosphates, Hexafluoroantimonates and Hexafluoroarsenates. Structure and Chemical Reactivity of Acyl Fluoride: Lewis Acid Fluoride Complexes1c. J. Am. Chem. Soc. 1962, 84, 14, 2733–2740. doi:10.1021/ja00873a019.
- ^ G. A. Olah; J. J. Svoboda (1972). Preparative Carbocation Chemistry. II1. Improved Preparation of Alkyloxocarbenium (Acyl) Hexafluoroantimonate Salts. Synthesis. doi:10.1055/s-1972-21872.
- ^ Milya G. Davlieva, Sergey V. Lindeman, Ivan S. Neretin and Jay K. Kochi. Structural effects of carbon monoxide coordination to carbon centers. π and σ bindings in aliphatic acylversus aromatic aroylcations. New J. Chem., 2004,28, 1568-1574. doi:10.1039/B407654K.