疊氮化亞汞
疊氮化亞汞 | |
---|---|
識別 | |
CAS號 | 38232-63-2 |
性質 | |
化學式 | Hg2(N3)2 |
莫耳質量 | 485.22 g·mol⁻¹ |
外觀 | 無色晶體 |
熔點 | 387 °C(爆炸)[1] |
溶解性(水) | 溶度積Ks=0.81×10-18[2] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
疊氮化亞汞是一種無機化合物,化學式為Hg2(N3)2,最早於1891年由西奧多·庫爾提烏斯合成得到。
製備與性質
疊氮化亞汞可由硝酸亞汞的硝酸或乙酸溶液和疊氮化鈉反應製得。[1]
它是無色單斜晶體,空間群P21/n,對日光敏感。[3]它和氨水反應,可以得到[Hg2N]N3。[4]
參考文獻
- ^ 1.0 1.1 Robillard, J.J. Possible Use of Certain Metallic Azides for the Development Field Controlled Dry Photographic Process. The Journal of Photographic Science (Informa UK Limited). 1971, 19 (2): 25–37. ISSN 0022-3638. doi:10.1080/00223638.1971.11737571.
- ^ Clever, H. Lawrence; Johnson, Susan A.; Derrick, M. Elizabeth. The Solubility of Mercury and Some Sparingly Soluble Mercury Salts in Water and Aqueous Electrolyte Solutions. Journal of Physical and Chemical Reference Data (AIP Publishing). 1985-07-01, 14 (3): 631–680. ISSN 0047-2689. doi:10.1063/1.555732.
- ^ Nockemann, Peter; Cremer, Ulrich; Ruschewitz, Uwe; Meyer, Gerd. Mercurous Azide, Hg2(N3)2. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2003, 629 (12-13): 2079–2082. ISSN 0044-2313. doi:10.1002/zaac.200300162.
- ^ Lund, Henrik; Oeckler, Oliver; Schröder, Thorsten; Schulz, Axel; Villinger, Alexander. Mercury Azides and the Azide of Millon’s Base. Angewandte Chemie International Edition (Wiley). 2013-08-26, 52 (41): 10900–10904. ISSN 1433-7851. doi:10.1002/anie.201305545.