叠氮化亚汞
叠氮化亚汞 | |
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识别 | |
CAS号 | 38232-63-2 |
性质 | |
化学式 | Hg2(N3)2 |
摩尔质量 | 485.22 g·mol⁻¹ |
外观 | 无色晶体 |
熔点 | 387 °C(爆炸)[1] |
溶解性(水) | 溶度积Ks=0.81×10-18[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
叠氮化亚汞是一种无机化合物,化学式为Hg2(N3)2,最早于1891年由西奥多·库尔提乌斯合成得到。
制备与性质
叠氮化亚汞可由硝酸亚汞的硝酸或乙酸溶液和叠氮化钠反应制得。[1]
它是无色单斜晶体,空间群P21/n,对日光敏感。[3]它和氨水反应,可以得到[Hg2N]N3。[4]
参考文献
- ^ 1.0 1.1 Robillard, J.J. Possible Use of Certain Metallic Azides for the Development Field Controlled Dry Photographic Process. The Journal of Photographic Science (Informa UK Limited). 1971, 19 (2): 25–37. ISSN 0022-3638. doi:10.1080/00223638.1971.11737571.
- ^ Clever, H. Lawrence; Johnson, Susan A.; Derrick, M. Elizabeth. The Solubility of Mercury and Some Sparingly Soluble Mercury Salts in Water and Aqueous Electrolyte Solutions. Journal of Physical and Chemical Reference Data (AIP Publishing). 1985-07-01, 14 (3): 631–680. ISSN 0047-2689. doi:10.1063/1.555732.
- ^ Nockemann, Peter; Cremer, Ulrich; Ruschewitz, Uwe; Meyer, Gerd. Mercurous Azide, Hg2(N3)2. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2003, 629 (12-13): 2079–2082. ISSN 0044-2313. doi:10.1002/zaac.200300162.
- ^ Lund, Henrik; Oeckler, Oliver; Schröder, Thorsten; Schulz, Axel; Villinger, Alexander. Mercury Azides and the Azide of Millon’s Base. Angewandte Chemie International Edition (Wiley). 2013-08-26, 52 (41): 10900–10904. ISSN 1433-7851. doi:10.1002/anie.201305545.