高氯酸钆

高氯酸钆
识别
CAS号	14017-52-8（无水） ; 15201-56-6（八水）
性质
化学式	Cl3GdO12
摩尔质量	455.6 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

高氯酸钆是一种无机化合物，化学式为Gd(ClO₄)₃。它可由氧化钆和高氯酸（70~72%）在80 °C反应得到。^[1]它可以和二𫫇烷形成无色的Gd(ClO₄)₃·9H₂O·4C₄H₈O₂配合物晶体。^[2]它和myo-肌醇、乙酸钠、氢氧化钠反应，可以得到含巨型分子簇{Gd₁₄₀}的配合物。^[1]它和氯化铬、2,2'-联吡啶在pH=5.1下反应，可以得到[GdCr(bipy)₂(OH)₂(H₂O)₆](ClO₄)₄·2H₂O。^[3]

参考文献

^ ^1.0 ^1.1 Xiu-Ying Zheng, You-Hong Jiang, Gui-Lin Zhuang, Da-Peng Liu, Hong-Gang Liao, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng. A Gigantic Molecular Wheel of {Gd 140 }: A New Member of the Molecular Wheel Family. Journal of the American Chemical Society. 2017-12-20, 139 (50): 18178–18181 [2023-03-15]. ISSN 0002-7863. doi:10.1021/jacs.7b11112. （原始内容存档于2023-03-15）（英语）.
^ Vicentini, Geraldo; Perrier, Madeleine; Giesbrecht, Ernesto. The reaction of dioxane with the perchlorate hydrates of a few transition metals. Chemische Berichte, 1961. 94: 1153-1155.
^ Zhong‐Yi Li, Xiao‐Qun Wang, Jian‐Jun Zhang, Shu‐Qin Liu, Jun Ni, Ying‐Ji Sun. Synthesis, Structures, and Magnetic Properties of Binuclear [CrLn] (Ln = Gd or Dy) and Trinuclear [Cr 2 Ln] (Ln = Gd, Dy, or Tb) Heterometallic Clusters with 2,2′‐Bipyridine as Ligand. European Journal of Inorganic Chemistry. 2015-12, 2015 (34): 5702–5707 [2023-03-15]. ISSN 1434-1948. doi:10.1002/ejic.201500786 （英语）.

[jacs-1] 1.0 ^1.1 Xiu-Ying Zheng, You-Hong Jiang, Gui-Lin Zhuang, Da-Peng Liu, Hong-Gang Liao, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng. A Gigantic Molecular Wheel of {Gd 140 }: A New Member of the Molecular Wheel Family. Journal of the American Chemical Society. 2017-12-20, 139 (50): 18178–18181 [2023-03-15]. ISSN 0002-7863. doi:10.1021/jacs.7b11112. （原始内容存档于2023-03-15）（英语）.

[2] Vicentini, Geraldo; Perrier, Madeleine; Giesbrecht, Ernesto. The reaction of dioxane with the perchlorate hydrates of a few transition metals. Chemische Berichte, 1961. 94: 1153-1155.

[3] Zhong‐Yi Li, Xiao‐Qun Wang, Jian‐Jun Zhang, Shu‐Qin Liu, Jun Ni, Ying‐Ji Sun. Synthesis, Structures, and Magnetic Properties of Binuclear [CrLn] (Ln = Gd or Dy) and Trinuclear [Cr 2 Ln] (Ln = Gd, Dy, or Tb) Heterometallic Clusters with 2,2′‐Bipyridine as Ligand. European Journal of Inorganic Chemistry. 2015-12, 2015 (34): 5702–5707 [2023-03-15]. ISSN 1434-1948. doi:10.1002/ejic.201500786 （英语）.

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