二氯汞基四羰基鐵

二氯汞基四羰基鐵
英文名	bis(chloromercuri)tetracarbonyliron
識別
CAS號	15281-84-2
SMILES	Cl[Hg][Fe](=C=O)(=C=O)(=C=O)(=C=O)[Hg]Cl;
性質
化學式	C4Cl2FeHg2O4
摩爾質量	639.97 g·mol−1
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

二氯汞基四羰基鐵是一種金屬有機化合物，化學式為Fe(CO)₄(HgCl)₂，它可由五羰基鐵在乙醇中和氯化汞反應得到。^[1]其分子中的一至兩個羰基可以被其它配體取代，生成Fe(CO)₂(py)₂(HgCl)₂等化合物。^[1]其氯汞基也能被其它金屬基取代，如和鋅反應，可以得到(ClZn)₂Fe(CO)₄；和Bu₃SnCl反應，得到(Bu₃Sn)₂Fe(CO)₄。^[2]它的熱分解產物是氧化鐵。^[3]

參考文獻

^ ^1.0 ^1.1 Lewis, J.; Wild, S. B. Chemistry of polynuclear compounds. IV. Some amine-substituted mercury halide-iron carbonyl compounds. J. Chem. Soc., Inorg., Phys., Theoret., 1966. 1: 69-72.
^ James M. Burlitch, Richard C. Winterton. Bis(chlorozinc)tetracarbonyliron: preparation, characterization and metathetical reactions with organotin chlorides. Inorganic Chemistry. 1979-08, 18 (8): 2309–2311 [2020-10-18]. ISSN 0020-1669. doi:10.1021/ic50198a053 （英語）.
^ ZAMIAN, José Roberto; MAURO, Antonio Eduardo; NUNES, Carolina Coimbra; DE ALMEIDA, Eduardo Tonon. Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I). Eclética Química. 2000, 25 (0): 89–95. ISSN 0100-4670. doi:10.1590/S0100-46702000000100008.

[Lewis-1] 1.0 ^1.1 Lewis, J.; Wild, S. B. Chemistry of polynuclear compounds. IV. Some amine-substituted mercury halide-iron carbonyl compounds. J. Chem. Soc., Inorg., Phys., Theoret., 1966. 1: 69-72.

[2] James M. Burlitch, Richard C. Winterton. Bis(chlorozinc)tetracarbonyliron: preparation, characterization and metathetical reactions with organotin chlorides. Inorganic Chemistry. 1979-08, 18 (8): 2309–2311 [2020-10-18]. ISSN 0020-1669. doi:10.1021/ic50198a053 （英語）.

[3] ZAMIAN, José Roberto; MAURO, Antonio Eduardo; NUNES, Carolina Coimbra; DE ALMEIDA, Eduardo Tonon. Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I). Eclética Química. 2000, 25 (0): 89–95. ISSN 0100-4670. doi:10.1590/S0100-46702000000100008.

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