二氯汞基四羰基铁

二氯汞基四羰基铁
英文名	bis(chloromercuri)tetracarbonyliron
识别
CAS号	15281-84-2
SMILES	Cl[Hg][Fe](=C=O)(=C=O)(=C=O)(=C=O)[Hg]Cl;
性质
化学式	C4Cl2FeHg2O4
摩尔质量	639.97 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

二氯汞基四羰基铁是一种金属有机化合物，化学式为Fe(CO)₄(HgCl)₂，它可由五羰基铁在乙醇中和氯化汞反应得到。^[1]其分子中的一至两个羰基可以被其它配体取代，生成Fe(CO)₂(py)₂(HgCl)₂等化合物。^[1]其氯汞基也能被其它金属基取代，如和锌反应，可以得到(ClZn)₂Fe(CO)₄；和Bu₃SnCl反应，得到(Bu₃Sn)₂Fe(CO)₄。^[2]它的热分解产物是氧化铁。^[3]

参考文献

^ ^1.0 ^1.1 Lewis, J.; Wild, S. B. Chemistry of polynuclear compounds. IV. Some amine-substituted mercury halide-iron carbonyl compounds. J. Chem. Soc., Inorg., Phys., Theoret., 1966. 1: 69-72.
^ James M. Burlitch, Richard C. Winterton. Bis(chlorozinc)tetracarbonyliron: preparation, characterization and metathetical reactions with organotin chlorides. Inorganic Chemistry. 1979-08, 18 (8): 2309–2311 [2020-10-18]. ISSN 0020-1669. doi:10.1021/ic50198a053 （英语）.
^ ZAMIAN, José Roberto; MAURO, Antonio Eduardo; NUNES, Carolina Coimbra; DE ALMEIDA, Eduardo Tonon. Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I). Eclética Química. 2000, 25 (0): 89–95. ISSN 0100-4670. doi:10.1590/S0100-46702000000100008.

[Lewis-1] 1.0 ^1.1 Lewis, J.; Wild, S. B. Chemistry of polynuclear compounds. IV. Some amine-substituted mercury halide-iron carbonyl compounds. J. Chem. Soc., Inorg., Phys., Theoret., 1966. 1: 69-72.

[2] James M. Burlitch, Richard C. Winterton. Bis(chlorozinc)tetracarbonyliron: preparation, characterization and metathetical reactions with organotin chlorides. Inorganic Chemistry. 1979-08, 18 (8): 2309–2311 [2020-10-18]. ISSN 0020-1669. doi:10.1021/ic50198a053 （英语）.

[3] ZAMIAN, José Roberto; MAURO, Antonio Eduardo; NUNES, Carolina Coimbra; DE ALMEIDA, Eduardo Tonon. Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I). Eclética Química. 2000, 25 (0): 89–95. ISSN 0100-4670. doi:10.1590/S0100-46702000000100008.

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