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1-溴-3,5-二甲苯

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1-溴-3,5-二甲苯
识别
CAS号 556-96-7  checkY
性质
化学式 C8H9Br
摩尔质量 185.06 g·mol−1
沸点 204 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

1-溴-3,5-二甲苯是一种有机化合物,化学式为C8H9Br。它可由3,5-二甲基苯胺经重氮化-溴化反应制得。[2]它和苯硼酸乙酸钯催化下反应,得到3,5-二甲基联苯。[3]它和环己基胺叔丁醇钠存在下反应,可以得到N-环己基-3,5-二甲基苯胺。[4]

参考文献

  1. ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2022-3-6].
  2. ^ Oberboersch, Stefan; Schunk, Stefan; Reich, Melanie; Hees, Sabine; Jostock, Ruth; Engels, Michael; Kless, Achim; Christoph, Thomas; Schiene, Klaus; Germann, Tieno; Bijsterveld, Edward. Preparation of 1-(phenylsulfonyl)​piperidines as bradykinin BK1 receptor inhibitors. 2008 WO 2008040492 A1.
  3. ^ Jairus L. Lamola, Paseka T. Moshapo, Cedric W. Holzapfel, Munaka Christopher Maumela. Evaluation of P-bridged biaryl phosphine ligands in palladium-catalysed Suzuki–Miyaura cross-coupling reactions. RSC Advances. 2021, 11 (43): 26883–26891 [2022-03-06]. ISSN 2046-2069. doi:10.1039/D1RA04947J (英语). 
  4. ^ Kent O. Kirlikovali, Eunho Cho, Tyler J. Downard, Lilit Grigoryan, Zheng Han, Sooji Hong, Dahee Jung, Jason C. Quintana, Vanessa Reynoso, Sooihk Ro, Yi Shen, Kevin Swartz, Elizabeth Ter Sahakyan, Alex I. Wixtrom, Brandon Yoshida, Arnold L. Rheingold, Alexander M. Spokoyny. Buchwald–Hartwig amination using Pd( i ) dimer precatalysts supported by biaryl phosphine ligands. Dalton Transactions. 2018, 47 (11): 3684–3688 [2022-03-06]. ISSN 1477-9226. doi:10.1039/C8DT00119G (英语).