甲酸镍
甲酸镍 | ||
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识别 | ||
CAS号 | 3349-06-2(无水) 15694-70-9(二水) | |
性质 | ||
化学式 | C2H2NiO4 | |
摩尔质量 | 148.73 g·mol−1 | |
溶解性(水) | 0.15 mol/L(二水,25 °C) | |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
甲酸镍是镍和甲酸形成的盐,化学式为Ni(HCOO)2。它可由甲酸钠和硫酸镍在热水中反应,冷却后析出得到。[1]它热分解生成金属镍。[2]它除了可以形成水合物外,还可以和氨或吡啶形成配合物。[3]
参考文献
- ^ Kaminskii, N. A. Production of nickel formate. Masloboino-Zhirovaya Promyshlennost, 1954. 19 (4): 31-32. ISSN 0368-8712.
- ^ Anna N. Puzan, Vyacheslav N. Baumer, Dmytro V. Lisovytskiy, Pavel V. Mateychenko. Structure transformations in nickel oxalate dihydrate NiC2O4·2H2O and nickel formate dihydrate Ni(HCO2)2·2H2O during thermal decomposition. Journal of Solid State Chemistry. 2018-10, 266: 133–142 [2022-03-23]. doi:10.1016/j.jssc.2018.07.005. (原始内容存档于2020-02-18) (英语).
- ^ Arnaiz Garcia, F. J.; Perez Manrique, M. M. Study of nickel formate and its addition products with ammonia, pyridine, and 4-methylpyridine. Ion (Madrid), 1976. 36 (420): 422-425. ISSN 0375-9091.