4,4'-二乙炔基联苯
4,4'-二乙炔基联苯 | |
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识别 | |
CAS号 | 38215-38-2 |
SMILES |
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性质 | |
化学式 | C16H10 |
摩尔质量 | 202.25 g·mol−1 |
外观 | 无色针状晶体[1] |
熔点 | 165.5~166.5 °C[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
4,4'-二乙炔基联苯是一种有机化合物,化学式为C16H10,它是二苯基丁二炔的同分异构体。它可以4,4'-二溴联苯和三甲基乙炔基硅烷在催化下反应,再与碱反应得到。[2]它在八羰基二钴催化下可以聚合。[3]
参考文献
- ^ 1.0 1.1 Tani, Hisaya; Toda, Fumio; Matsumiya, Koreyasu (1963). Oligomers and Polymers Containing Triple Bonds. I. Derivatives of Ethynylbiphenyl and Ethynylfluorene. Bulletin of the Chemical Society of Japan, 36(4), 391–396. doi:10.1246/bcsj.36.391
- ^ Sourav Bhowmick; et al. Pyrazine-based donor tectons: synthesis, self-assembly and characterization. RSC Adv., 2016,6, 8992-9001. doi:10.1039/C5RA21484J.
- ^ Shengwen Yuan; et al. Microporous polyphenylenes with tunable pore size for hydrogenstorage. Chem. Commun., 2010,46, 4547-4549. doi:10.1039/C0CC00235F.