2-吡啶基溴化鎂
2-吡啶基溴化鎂 | |
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識別 | |
CAS號 | 21970-13-8 |
SMILES |
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性質 | |
化學式 | C5H4BrMgN |
摩爾質量 | 182.3 g·mol−1 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
2-吡啶基溴化鎂是一種有機鎂化合物,化學式為C5H4BrMgN。它可由2-溴吡啶和鎂在四氫呋喃中反應製得。[1]它和乙醯氯在N-甲基吡咯烷酮存在下反應,可以得到2-乙醯基吡啶。[2]
參考文獻
- ^ Cheng-Kun Li, Ze-Kun Tao, Adedamola Shoberu, Wei Zhang, and Jian-Ping Zou. Copper-Catalyzed Cross-Coupling of Alkyl and Phosphorus Radicals for C(sp3)–P Bond Formation. Org. Lett. 2022, 24, 32, 6083–6087. doi:10.1021/acs.orglett.2c02454.
- ^ Maravanhalli Sidde Gowda, Sushanth Sudhir Pande, Ramesha Andagar Ramakrishna and Kandikere Ramaiah Prabhu. Acylation of Grignard reagents mediated by N-methylpyrrolidone: A remarkable selectivity for the synthesis of ketones. Org. Biomol. Chem., 2011,9, 5365-5368. doi:10.1039/C1OB05780D.