乙醯丙酮鏑

乙醯丙酮鏑
英文名	Tris(acetylacetonato)dysprosium
別名	三(2,4-戊二酮)鏑
識別
CAS號	14637-88-8
PubChem	14455608
ChemSpider	14982472
SMILES	C/C(=C/C(=O)C)/[O-].C/C(=C/C(=O)C)/[O-].C/C(=C/C(=O)C)/[O-].[Dy+3];
性質
化學式	C15H21DyO6
摩爾質量	459.82 g·mol−1
外觀	白色晶體
熔點	103 °C（376 K）
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

乙醯丙酮鏑是一種配位化合物，化學式為Dy(C₅H₇O₂)₃，或簡寫為Dy(acac)₃。

製備及性質

乙醯丙酮鏑可由金屬鏑^[2]或三氫化鏑^[1]和乙醯丙酮反應製得。以鏑陰極在乙醯丙酮的乙醇溶液中電解，可以得到Dy(acac)₃·EtOH·0.5Hacac（其中Hacac表示乙醯丙酮），對其加熱，經Dy(acac)₃·EtOH生成Dy(acac)₃。^[3]其無水物在乾燥的氣氛中穩定，在潮濕空氣中形成水合物。^[4]它在乙腈的甲醇溶液中可以形成Dy(acac)₃·2CH₃OH和Dy(acac)₃·CH₃OH·CH₃CN。^[5]

用途

乙醯丙酮鏑可用於催化降冰片烯和四氯化碳的加成反應。^[6]

參考文獻

^ ^1.0 ^1.1 ^1.2 Janice M. Koehler, William G. Bos. A novel synthesis of some anhydrous rare earth acetylacetonates. Inorganic and Nuclear Chemistry Letters. 1967-12, 3 (12): 545–548 [2021-09-20]. doi:10.1016/0020-1650(67)80023-0 （英語）.
^ J.R. Blackborow, C.R. Eady, E.A.Koerner Von Gustorf, A. Scrivanti, O. Wolfbeis. Chemical syntheses with metal atoms. Journal of Organometallic Chemistry. 1976-03, 108 (3): C32–C34 [2021-09-20]. doi:10.1016/S0022-328X(00)92025-4. （原始內容存檔於2018-06-26）（英語）.
^ Kostyuk, N. N.; Shirokii, V. L.; Vinokurov, I. I.; Maier, N. A. Electrochemical synthesis of dysprosium(III) acetylacetonate complex and its thermolysis. Zhurnal Obshchei Khimii, 1994. 64 (9): 1432-1434. ISSN 0044-460X. （俄文）
^ Trembovetskii, G. V.; Martynenko, L. I.; Murav'eva, I. A.; Spitsyn, V. Synthesis and study of volatile rare earth acetylacetonates. Doklady Akademii Nauk SSSR, 1984. 277 (6): 1411-1414. ISSN: 0002-3264. （俄文）
^ Pod'yachev, S. N.; Mustafina, A. R.; Vul'fson, S. G. Structure of tris(acetylacetonato)dysprosium and its monoadduct with acetonitrile in a methanol solution. Zhurnal Neorganicheskoi Khimii, 1994. 39 (1): 67-70. ISSN 0044-457X. （俄文）
^ R. I. Khusnutdinov, T. M. Oshnyakova. Tetrachloromethane addition to norbornene catalyzed by lanthanide(III) compounds. Russian Journal of Organic Chemistry. 2014-02, 50 (2): 303–305 [2021-09-20]. ISSN 1070-4280. doi:10.1134/S1070428014020304 （英語）.

[Janice-1] 1.0 ^1.1 ^1.2 Janice M. Koehler, William G. Bos. A novel synthesis of some anhydrous rare earth acetylacetonates. Inorganic and Nuclear Chemistry Letters. 1967-12, 3 (12): 545–548 [2021-09-20]. doi:10.1016/0020-1650(67)80023-0 （英語）.

[2] J.R. Blackborow, C.R. Eady, E.A.Koerner Von Gustorf, A. Scrivanti, O. Wolfbeis. Chemical syntheses with metal atoms. Journal of Organometallic Chemistry. 1976-03, 108 (3): C32–C34 [2021-09-20]. doi:10.1016/S0022-328X(00)92025-4. （原始內容存檔於2018-06-26）（英語）.

[3] Kostyuk, N. N.; Shirokii, V. L.; Vinokurov, I. I.; Maier, N. A. Electrochemical synthesis of dysprosium(III) acetylacetonate complex and its thermolysis. Zhurnal Obshchei Khimii, 1994. 64 (9): 1432-1434. ISSN 0044-460X. （俄文）

[4] Trembovetskii, G. V.; Martynenko, L. I.; Murav'eva, I. A.; Spitsyn, V. Synthesis and study of volatile rare earth acetylacetonates. Doklady Akademii Nauk SSSR, 1984. 277 (6): 1411-1414. ISSN: 0002-3264. （俄文）

[5] Pod'yachev, S. N.; Mustafina, A. R.; Vul'fson, S. G. Structure of tris(acetylacetonato)dysprosium and its monoadduct with acetonitrile in a methanol solution. Zhurnal Neorganicheskoi Khimii, 1994. 39 (1): 67-70. ISSN 0044-457X. （俄文）

[6] R. I. Khusnutdinov, T. M. Oshnyakova. Tetrachloromethane addition to norbornene catalyzed by lanthanide(III) compounds. Russian Journal of Organic Chemistry. 2014-02, 50 (2): 303–305 [2021-09-20]. ISSN 1070-4280. doi:10.1134/S1070428014020304 （英語）.

[1]

[2]

[3]

[4]

[5]

[6]