四氟氧化钨

四氟氧化钨
识别
CAS号	13520-79-1
PubChem	139487
SMILES	O=[W]F(F)(F)F;
InChI	1S/4FH.O.W/h4*1H;;;
性质
化学式	WOF4
摩尔质量	275.83 g·mol⁻¹
外观	无色晶体
密度	5.07 g/cm3
熔点	110 °C（383 K）（）
沸点	185 °C（458 K）
溶解性（水）	反应
溶解性	可溶于氯仿; 微溶于二硫化碳
结构
晶体结构	单斜晶系
危险性
欧盟分类	未列出
相关物质
其他阴离子	四氯氧化钨; 四溴氧化钨
其他阳离子	四氟氧化钼
相关化学品	二氟二氧化钨
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

四氟氧化钨是一种无机化合物，化学式为WOF₄，易水解。其反应活性类似于六氟化钨。^[4]

制备

WOF₄可由氟气于230~400℃和三氧化钨反应得到：^[4]

WO₃ + 2 F₂ → WOF₄ + 2 O₂

它也可以由钨和氧气和氟气的混合物在高温下反应而成，^[1]六氟化钨的部分水解也能产生WOF₄：^[5]

{\ce {WF6 + H2O -> WOF4 + 2 HF}}

四氯氧化钨和氟化氢的反应也会产生WOF₄：^[3]

{\ce {WOCl4 + 4HF -> WOF4 + 4HCl}}

WOF₄还可以由氟化铅和三氧化钨在700 °C下反应而成：^[3]

{\ce {2PbF2 + WO3 -> WOF4 + 2PbO}}

性质

四氟氧化钨是无色固体，会水解成钨酸：^[1]^[5]

{\ce {WOF4 + 2 H2O -> WO3 + 4 HF}}

固态的WOF₄之前假定为四聚体结构，^[6]后来受到光谱学研究的质疑。在气态下，该分子具有单体结构。^[7]四氟氧化钨可以和乙腈等配体形成配合物。^[8]^[9]

参考文献

^ ^1.0 ^1.1 ^1.2 Perry, Dale L.; Phillips, Sidney L. Handbook of inorganic compounds. Boca Raton: CRC Press. 1995: 428. ISBN 0-8493-8671-3. OCLC 32347397.
^ ^2.0 ^2.1 ^2.2 Haynes, William M.; Lide, David R.; Bruno, Thomas J. CRC handbook of chemistry and physics : a ready-reference book of chemical and physical data.. Boca Raton, Florida. 2017: 104. ISBN 978-1-4987-5429-3. OCLC 957751024.
^ ^3.0 ^3.1 ^3.2 ^3.3 Lassner, Erik; Schubert, Wolf-Dieter. Tungsten : Properties, Chemistry, Technology of the Element, Alloys, and Chemical Compounds. Boston, MA. 1999: 168. ISBN 1-4615-4907-8. OCLC 1113605323.
^ ^4.0 ^4.1 朱文祥. 无机化合物制备手册. 化学工业出版社, 2006. pp 269 【Ⅵ-132】四氟氧钨. ISBN 7-5025-8537-0
^ ^5.0 ^5.1 Mendicino, L.; Electrochemical Society. Dielectric Science and Technology Division; Electrochemical Society. Meeting; Symposium on Environmental Issues with Materials and Processes in the Electronics and Semiconductor Industries. Environmental issues with materials and processes for the electronics and semiconductor industries : proceedings of the fourth international symposium. Pennington, NJ: Electrochemical Society. 2001: 180. ISBN 1-56677-312-1. OCLC 48710248.
^ Lippard, Stephen J. Progress in inorganic chemistry. Volume 28. New York, N.Y.: Wiley. 1981: 245. ISBN 978-0-470-16679-6. OCLC 123541241.
^ Johnson, B. F. G. Inorganic chemistry of the transition elements. Volume 4, A review of the literature published between October 1973 and September 1974. London: Chemical Society. 1976: 138. ISBN 978-1-84755-645-5. OCLC 820579758.
^ Levason, William; Reid, Gillian; Zhang, Wenjian. Coordination complexes of the tungsten(VI) oxide fluorides WOF4 and WO2F2 with neutral oxygen- and nitrogen-donor ligands. Journal of Fluorine Chemistry (Elsevier BV). 2016, 184: 50–57. ISSN 0022-1139. doi:10.1016/j.jfluchem.2016.02.003.
^ Arnaudet, Lucile; Bougon, Roland; Charpin, Pierrette; Isabey, Jacques; Lance, Monique; Nierlich, Martine; Vigner, Julien. Preparation, characterization, and crystal structure of the adducts WOF4.nC5H5N (n = 1, 2). Inorganic Chemistry (American Chemical Society (ACS)). 1989, 28 (2): 257–262. ISSN 0020-1669. doi:10.1021/ic00301a020.

[Dale_L._Perry-1] 1.0 ^1.1 ^1.2 Perry, Dale L.; Phillips, Sidney L. Handbook of inorganic compounds. Boca Raton: CRC Press. 1995: 428. ISBN 0-8493-8671-3. OCLC 32347397.

[William_M._Haynes-2] 2.0 ^2.1 ^2.2 Haynes, William M.; Lide, David R.; Bruno, Thomas J. CRC handbook of chemistry and physics : a ready-reference book of chemical and physical data.. Boca Raton, Florida. 2017: 104. ISBN 978-1-4987-5429-3. OCLC 957751024.

[Erik_Lassner,_Wolf-Dieter_Schubert-3] 3.0 ^3.1 ^3.2 ^3.3 Lassner, Erik; Schubert, Wolf-Dieter. Tungsten : Properties, Chemistry, Technology of the Element, Alloys, and Chemical Compounds. Boston, MA. 1999: 168. ISBN 1-4615-4907-8. OCLC 1113605323.

[Zhu-4] 4.0 ^4.1 朱文祥. 无机化合物制备手册. 化学工业出版社, 2006. pp 269 【Ⅵ-132】四氟氧钨. ISBN 7-5025-8537-0

[Laura_Mendicino-5] 5.0 ^5.1 Mendicino, L.; Electrochemical Society. Dielectric Science and Technology Division; Electrochemical Society. Meeting; Symposium on Environmental Issues with Materials and Processes in the Electronics and Semiconductor Industries. Environmental issues with materials and processes for the electronics and semiconductor industries : proceedings of the fourth international symposium. Pennington, NJ: Electrochemical Society. 2001: 180. ISBN 1-56677-312-1. OCLC 48710248.

[Stephen_J._Lippard-6] Lippard, Stephen J. Progress in inorganic chemistry. Volume 28. New York, N.Y.: Wiley. 1981: 245. ISBN 978-0-470-16679-6. OCLC 123541241.

[B._F._G._Johnson-7] Johnson, B. F. G. Inorganic chemistry of the transition elements. Volume 4, A review of the literature published between October 1973 and September 1974. London: Chemical Society. 1976: 138. ISBN 978-1-84755-645-5. OCLC 820579758.

[8] Levason, William; Reid, Gillian; Zhang, Wenjian. Coordination complexes of the tungsten(VI) oxide fluorides WOF4 and WO2F2 with neutral oxygen- and nitrogen-donor ligands. Journal of Fluorine Chemistry (Elsevier BV). 2016, 184: 50–57. ISSN 0022-1139. doi:10.1016/j.jfluchem.2016.02.003.

[9] Arnaudet, Lucile; Bougon, Roland; Charpin, Pierrette; Isabey, Jacques; Lance, Monique; Nierlich, Martine; Vigner, Julien. Preparation, characterization, and crystal structure of the adducts WOF4.nC5H5N (n = 1, 2). Inorganic Chemistry (American Chemical Society (ACS)). 1989, 28 (2): 257–262. ISSN 0020-1669. doi:10.1021/ic00301a020.

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查论编卤氧化物
+2价	Hg₂OCl
+3价	FeOCl SbOCl BiOF BiOCl BiOBr BiOI CfOF CfOCl NOCl
+4价	COCl₂ SOF₂ SOCl₂ SOBr₂ ZrOCl₂ SeOBr₂ SeOCl₂
+5价	POF₃ POCl₃ VOF₃ VOCl₃ NbOCl₃ TaOCl₃ ClO₂F ClOF₃ IO₂F IOF₃
+6价	CrO₂F₂ CrO₂Cl₂ MoO₂Cl₂ MoOCl₄ WO₂F₂ WOF₄ WO₂Cl₂ WOCl₄ OsOCl₄ WO₂Br₂ WOBr₄ SO₂F₂ SO₂Cl₂ SeO₂F₂ UO₂F₂ UO₂Cl₂
+7价	MnO₃F TcO₃F ReOF₅ ReO₂F₃ ReO₃F ClO₃F IO₃F（俄语：Фторид-триоксид_иода） IO₂F₃（俄语：Трифторид-диоксид_иода） IOF₅
+8价	OsO₂F₄ OsO₃F₂ XeO₂F₄ XeO₃F₂