三氨三羰基铬
三氨三羰基铬 | |
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识别 | |
CAS号 | 14974-11-9 |
SMILES |
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性质 | |
化学式 | C3H9CrN3O3 |
摩尔质量 | 187.12 g·mol−1 |
外观 | 亮黄色晶体[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
三氨三羰基铬是一种有机铬化合物,化学式为Cr(CO)3(NH3)3。它可由六羰基铬和氢氧化钾在乙醇中(或和四甲基氢氧化铵在甲醇中[1])和浓氨水反应制得。[2]它可以和芳烃(arene)反应,形成(arene)Cr(CO)3配合物。[3]
参考文献
- ^ 1.0 1.1 Timothy J. McNeese; Maurice B. Cohen; Bruce M. Foxman. Synthesis, structure, and reactivity of a polynuclear chromium tetraanion, tetrakis[(μ3-methoxo)tricarbonylchromate(0)]. Organometallics 1984, 3, 4, 552–556. doi:10.1021/om00082a007
- ^ Tucker M. Folsom; Gulzar A. Bhat; Ahmed Z. Rashad; Donald J. Darensbourg. Approach for Introducing a Single Metal Complex into a Polymer Chain: Metallo-Chain Transfer Agents in CO2 or COS/Epoxide Copolymerization Processes. Macromolecules 2019, 52, 14, 5217–5222. doi:10.1021/acs.macromol.9b00906.
- ^ E. V. Sazonova;A. N. Artemov;V. I. Faerman;N. A. Aksenova;A. A. Timofeeva;Yu. A. Zaytseva;N. V. Somov;N. Yu. Grishina; (2021). Synthesis of (η6-arene)tricarbonylchromium derivatives of 1,4-dihydro-3,1-benzoxazines . Russian Chemical Bulletin, 70 (1). doi:10.1007/s11172-021-3073-y