4-氯異丙苯
4-氯異丙苯 | |
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識別 | |
CAS號 | 2621-46-7 |
SMILES |
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性質 | |
化學式 | C9H11Cl |
摩爾質量 | 154.64 g·mol−1 |
熔點 | −12.3 °C[1] |
沸點 | 198.3 °C[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
4-氯異丙苯是一種有機氯化合物,化學式為C9H11Cl。它可由異丙苯和氯氣在乙酸中,或和次氯酸叔丁酯在沸石存在下於乙腈中反應製得,該反應會產生少量的2-氯異丙苯。[2]在氯化亞鐵催化下,它可以被過氧化氫氧化為4'-氯苯乙酮。[3]
參考文獻
- ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2024-07-02].
- ^ Smith, Keith; Butters, Michael; Nay, Barry. Highly para-Selective Mono-Chlorination of Aromatic Compounds Under Mild Conditions by t-Butyl Hypochlorite in the Presence of Zeolites. Synthesis, 1985 (12), 1157–1158. doi:10.1055/s-1985-31462
- ^ Ning Xu, Lulu Zhou, Linlin Zhao, Mengying Guo, Linlin Yang, Wei Han. Iron-Catalyzed Oxidative C−C Bond Cleavage of Unstrained Tertiary Alkyl Aromatics to Arylketones. Advanced Synthesis & Catalysis. 2023. 365 (15). doi:10.1002/adsc.202300410.