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4-氯異丙苯

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4-氯異丙苯
識別
CAS號 2621-46-7  checkY
SMILES
 
  • ClC1=CC=C(C=C1)C(C)C
性質
化學式 C9H11Cl
摩爾質量 154.64 g·mol−1
熔點 −12.3 °C[1]
沸點 198.3 °C[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

4-氯異丙苯是一種有機氯化合物,化學式為C9H11Cl。它可由異丙苯氯氣乙酸中,或和次氯酸叔丁酯沸石存在下於乙腈中反應製得,該反應會產生少量的2-氯異丙苯[2]氯化亞鐵催化下,它可以被過氧化氫氧化為4'-氯苯乙酮[3]

參考文獻

  1. ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2024-07-02].
  2. ^ Smith, Keith; Butters, Michael; Nay, Barry. Highly para-Selective Mono-Chlorination of Aromatic Compounds Under Mild Conditions by t-Butyl Hypochlorite in the Presence of Zeolites. Synthesis, 1985 (12), 1157–1158. doi:10.1055/s-1985-31462
  3. ^ Ning Xu, Lulu Zhou, Linlin Zhao, Mengying Guo, Linlin Yang, Wei Han. Iron-Catalyzed Oxidative C−C Bond Cleavage of Unstrained Tertiary Alkyl Aromatics to Arylketones. Advanced Synthesis & Catalysis. 2023. 365 (15). doi:10.1002/adsc.202300410.