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氟代醇

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氟代醇(英語:Fluoroalcohol,或稱為氟醇)是指既帶有羥基官能團又帶有碳-氟鍵有機化合物,這類化合物通常具有獨特的溶劑性質[1]

全氟醇

所有的碳-氫鍵碳-氟鍵取代的氟代醇被稱為全氟醇(英語:Perfluoroalcohol),最簡單的全氟醇是三氟甲醇。大部分的全氟伯醇和全氟仲醇不穩定,如三氟甲醇會在加熱下消去一個氟化氫生成碳酰氟[2],此反應可逆[3]

CF3OH ⇌ COF2 + HF (I)

另見

參考文獻

  1. ^ Ivan A. Shuklov, Natalia V. Dubrovina, Armin Börner. Fluorinated Alcohols as Solvents, Cosolvents and Additives in Homogeneous Catalysis: Benefits from the Use of Fluorinated Alcohols in Homogeneous Catalysis. Synthesis. 2007: 2925–2943. doi:10.1055/s-2007-983902. 
  2. ^ Schneider, W. F. Energetics and Mechanism of Decomposition of CF3OH. J. Phys. Chem. 1996, 100: 6097–6103. doi:10.1021/jp952703m. 
  3. ^ Cheburkov, Yuri; Lillquist, Gerald J. Perfluoroalcohols. Journal of Fluorine Chemistry. 2002, 118: 123–126. doi:10.1016/S0022-1139(02)00204-X.