NU-1000
| NU-1000 | |
|---|---|
| |
| 識別 | |
| CAS號 | 1446138-63-1 
|
| 性質 | |
| 化學式 | C88H60O32Zr6 |
| 摩爾質量 | 2176.74 g·mol−1 |
| 外觀 | 黃色晶體[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
NU-1000是由鋯和1,3,6,8-四(4-羧基苯基)芘（H4L）構成的介孔金屬有機框架材料，化學式為C88H60O32Zr6，最初於美國西北大學（Northwestern University）合成，它的Zr6簇具有八面體結構，簇的三角面與μ3-氧或μ3-羥基相連。[2]
合成
NU-1000可由四氯化鋯、苯甲酸和H4L在120 °C於DMF中反應得到。[3]
相關化合物
NU-1000的異構體ISO-NU-1000可由四氯化鋯和4,5,9,10-四(4-羧基苯基)芘在甲酸存在下反應得到，它的孔徑和NU-1000相比有所變化。[4]
參考文獻
- ^ Node Distortion as a Tunable Mechanism for Negative Thermal Expansion in Metal–Organic Frameworks. J. Am. Chem. Soc. 2023, 145, 1, 268–276. doi:10.1021/jacs.2c09877.
- ^ Design and Advanced Manufacturing of NU-1000 Metal–Organic Frameworks with Future Perspectives for Environmental and Renewable Energy Applications. Small, 2023. 2306353. doi:10.1002/smll.202306353.
- ^ Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies. J. Am. Chem. Soc. 2013, 135, 45, 16801–16804. doi:10.1021/ja408959g.
- ^ Isomer of NU-1000 with a Blocking c-pore Exhibits High Water–Vapor Uptake Capacity and Greatly Enhanced Cycle Stability. J. Am. Chem. Soc. 2023, 145, 7, 4150–4157. doi:10.1021/jacs.2c12362.