六氟磷酸銅
| 六氟磷酸銅 | ||
|---|---|---|
| ||
| 英文名 | Copper(II) hexafluorophosphate | |
| 識別 | ||
| CAS號 | 117288-37-6 
| |
| 性質 | ||
| 化學式 | Cu(PF6)2 | |
| 摩爾質量 | 353.47 g·mol⁻¹ | |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | ||
六氟磷酸銅是一種無機化合物，化學式為Cu(PF6)2，其中PF6−為非配位陰離子[1]。
製備
六氟磷酸銅可由硝酸銅和六氟磷酸銨按1：2化學計量比反應得到。[2]
- Cu(NO3)2 + 2 NH4PF6 → Cu(PF6)2 + 2 NH4NO3
配合物
六氟磷酸銅可以形成配合物[Cu(L)2ONC(CN)2]PF6（L=鄰二氮菲或2,2'-聯吡啶）。[3]
參考文獻
- ^ Honeychuck, R. V.; Hersh, W. H. Coordination of "Noncoordinating" Anions: Synthesis, Characterization, and X-ray Crystal Structures of Fluorine-Bridged [SbF6]−, [BF4]−, and [PF6]− Adducts of [R3P(CO)3(NO)W]+. An Unconventional Order of Anion Donor Strength. Inorganic Chemistry. 1989, 28 (14): 2869–2886. doi:10.1021/ic00313a034.
- ^ G Mukherjee，K Biradha. Coordination Polymers Containing M2L2 and M4L4 Metallacylces of Bis(pyridylcarboxamido)alkanes with an Odd Number of −(CH2)– Groups as Spacers: Guest Inclusion and Networks Recognition via α Sheet. Crystal Growth & Design, 2013, 13(9):4100–4109
- ^ Potocnak, I.; Vavra, M.; Jager, L.; et al. Ligand rigidity and the shape of the coordination polyhedra in five-coordinated copper(II) complexes with nitrosodicyanmethanide. Monograph Series of the International Conferences on Coordination Chemistry held periodically at Smolenice in Slovakia (2005)7, 306-312
拓展閱讀
- AF Clifford，HC Beachell，WM Jack. The hydrogen fluoride solvent system—I A qualitative survey of acids. Journal of Inorganic & Nuclear Chemistry, 1957, 5(1):57-70