三氟甲磺酸铥

三氟甲磺酸铥
识别
CAS号	141478-68-4（无水） ; 74660-76-7（九水，结晶水） ; 74625-08-4（九水，配位水）
性质
化学式	C3F9O9S3Tm
摩尔质量	616.14 g·mol−1
外观	固体
密度	2.152 g·cm-3（九水）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

三氟甲磺酸铥是一种无机化合物，化学式为Tm(CF₃SO₃)₃。它可由氧化铥和三氟甲磺酸反应制得，从溶液中可以结晶出九水合物。^[1]从九水合物晶体占位因子（occupancy factor）的精修得出，每个Tm³⁺的水合数为8.84(5)。^[2]它和石墨化钾在dme中反应，可以得到二价铥的化合物[Tm(CF₃SO₃)₂(dme)₂]_n。^[3]

参考文献

^ Congting SunOrcid, Xiaoyan Chen, and Dongfeng Xue. Hydrogen Bonding Dependent Mesoscale Framework in Crystalline Ln(H₂O)₉(CF₃SO₃)₃. Cryst. Growth Des. 2017, 17, 5, 2631–2638. doi:10.1021/acs.cgd.7b00145.
^ Abbasi, Alireza; Lindqvist-Reis, Patric; Eriksson, Lars; Sandstroem, Dick; Lidin, Sven; Persson, Ingmar; Sandstroem, Magnus. Highly Hydrated Cations: Deficiency, Mobility, and Coordination of Water in Crystalline Nonahydrated Scandium(III), Yttrium(III), and Lanthanoid(III) Trifluoromethanesulfonates. Chemistry - A European Journal (2005), 11(14), 4065-4077. doi:10.1002/chem.200401339.
^ Xemard, Mathieu; Jaoul, Arnaud; Cordier, Marie; Molton, Florian; Cador, Olivier ; Le Guennic, Boris ; Duboc, Carole; Maury, Olivier; Clavaguera, Carine; Nocton, Gregory. Divalent Thulium Triflate: A Structural and Spectroscopic Study. Angewandte Chemie, International Edition (2017), 56(15), 4266-4271. doi:10.1002/anie.201700576.

[1] Congting SunOrcid, Xiaoyan Chen, and Dongfeng Xue. Hydrogen Bonding Dependent Mesoscale Framework in Crystalline Ln(H₂O)₉(CF₃SO₃)₃. Cryst. Growth Des. 2017, 17, 5, 2631–2638. doi:10.1021/acs.cgd.7b00145.

[2] Abbasi, Alireza; Lindqvist-Reis, Patric; Eriksson, Lars; Sandstroem, Dick; Lidin, Sven; Persson, Ingmar; Sandstroem, Magnus. Highly Hydrated Cations: Deficiency, Mobility, and Coordination of Water in Crystalline Nonahydrated Scandium(III), Yttrium(III), and Lanthanoid(III) Trifluoromethanesulfonates. Chemistry - A European Journal (2005), 11(14), 4065-4077. doi:10.1002/chem.200401339.

[3] Xemard, Mathieu; Jaoul, Arnaud; Cordier, Marie; Molton, Florian; Cador, Olivier ; Le Guennic, Boris ; Duboc, Carole; Maury, Olivier; Clavaguera, Carine; Nocton, Gregory. Divalent Thulium Triflate: A Structural and Spectroscopic Study. Angewandte Chemie, International Edition (2017), 56(15), 4266-4271. doi:10.1002/anie.201700576.

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