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4-硝基苯甲腈

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维基百科，自由的百科全书
4-硝基苯甲腈
别名 对硝基苯甲腈
4-氰基硝基苯
识别
CAS号 619-72-7  checkY
性质
化学式 C7H4N2O2
摩尔质量 148.12 g·mol−1
密度 1.430 g·cm−3[1]
熔点 148 °C（421 K）[2]
沸点 308 °C（581 K）[3]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

4-硝基苯甲腈是一种有机化合物，化学式为C7H4N2O2。它可由4-硝基苯甲醇的氨氧化反应制得，[4]或由4-硝基溴苯和氰化钠在钯催化下反应得到。[5]它可以被水合肼或硼氢化钠还原为4-氰基苯胺。[6][7]

参考文献

  1. ^ T. Higashi, K. Osaki. p -Nitrobenzonitrile. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 1977-07-01, 33 (7): 2337–2339 [2021-12-22]. ISSN 0567-7408. doi:10.1107/S0567740877008425. （原始内容存档于2021-12-22）. 
  2. ^ Mona Hosseini Sarvari. ZnO/CH 3 COCl: A New and Highly Efficient Catalyst for Dehydration of Aldoximes into Nitriles Under Solvent-Free Condition. Synthesis. 2005-02-14, 2005 (05): 787–790 [2021-12-22]. ISSN 0039-7881. doi:10.1055/s-2005-861826. （原始内容存档于2018-06-02） （英语）. 
  3. ^ I. G. Zenkevich. Physicochemical constants as a factor determining the need for the derivatization of organic substances in analysis by gas chromatography. Journal of Analytical Chemistry. 2010-03, 65 (3): 267–275 [2021-12-22]. ISSN 1061-9348. doi:10.1134/S106193481003010X （英语）. 
  4. ^ Guofu Zhang, Guihua Zhang, Jie Lei, Shasha Li, Shengjun Xu, Chengrong Ding, Shang Shan. Aerobic alcohol ammoxidation catalyzed by copper(I)/amino acid: a scalable protocol to nitriles. Chemical Research in Chinese Universities. 2016-08, 32 (4): 586–593 [2021-12-22]. ISSN 1005-9040. doi:10.1007/s40242-016-6067-9 （英语）. 
  5. ^ Alexander V. Ushkov, Vladimir V. Grushin. Rational Catalysis Design on the Basis of Mechanistic Understanding: Highly Efficient Pd-Catalyzed Cyanation of Aryl Bromides with NaCN in Recyclable Solvents. Journal of the American Chemical Society. 2011-07-20, 133 (28): 10999–11005 [2021-12-22]. ISSN 0002-7863. doi:10.1021/ja2042035 （英语）. 
  6. ^ Binbin Feng, Qionghao Xu, Xiaoxue Wu, Chunlin Ye, Yanghe Fu, De-Li Chen, Fumin Zhang, Weidong Zhu. MOF-derived N-doped carbon composites embedded with Fe/Fe3C nanoparticles as highly chemoselective and stable catalysts for catalytic transfer hydrogenation of nitroarenes. Applied Surface Science. 2021-08, 557: 149837 [2021-12-22]. doi:10.1016/j.apsusc.2021.149837 （英语）. 
  7. ^ Saravanan Krishnan, Paresh N. Patel, Kalpattu K. Balasubramanian, Anju Chadha. Yeast supported gold nanoparticles: an efficient catalyst for the synthesis of commercially important aryl amines. New Journal of Chemistry. 2021, 45 (4): 1915–1923 [2021-12-22]. ISSN 1144-0546. doi:10.1039/D0NJ04542J （英语）. 
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