3-溴氧杂环丁烷

3-溴氧杂环丁烷
识别
CAS号	39267-79-3
SMILES	BrC1COC1;
性质
化学式	C3H5BrO
摩尔质量	136.98 g·mol−1
沸点	125~126 °C; 66 °C（97 torr）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

3-溴氧杂环丁烷（3-溴𫫇丁环）是一种有机溴化合物，化学式为C₃H₅BrO。它可由4-甲苯磺酸-3-氧杂环丁酯和碱金属溴化物在三乙二醇中加热反应得到。^[1]它和其它溴代烃一样，可以参与偶联反应，如和丙烯酸苯酯在催化下反应，可以得到3-氧杂环丁基丙酸苯酯；^[2]它和2-乙炔基吡啶在叠氮化钠存在下反应，可以得到2-[1-(3-氧杂环丁基)-1H-1,2,3-三唑-4-基]吡啶。^[3]

参考文献

^ ^1.0 ^1.1 J. A. Wojtowicz, R. J. Polak. 3-Substituted oxetanes. The Journal of Organic Chemistry. 1973-06, 38 (11): 2061–2066 [2022-03-22]. ISSN 0022-3263. doi:10.1021/jo00951a020 （英语）.
^ Randolph A. Escobar, Jeffrey W. Johannes. Reductive Radical Conjugate Addition of Alkyl Electrophiles Catalyzed by a Cobalt/Iridium Photoredox System. Organic Letters. 2021-08-06, 23 (15): 6046–6051 [2022-03-22]. ISSN 1523-7060. doi:10.1021/acs.orglett.1c02114 （英语）.
^ Andrew R. Bogdan, Neal W. Sach. The Use of Copper Flow Reactor Technology for the Continuous Synthesis of 1,4-Disubstituted 1,2,3-Triazoles. Advanced Synthesis & Catalysis. 2009-04, 351 (6): 849–854 [2022-03-22]. doi:10.1002/adsc.200800758. （原始内容存档于2022-03-22）（英语）.

[woj-1] 1.0 ^1.1 J. A. Wojtowicz, R. J. Polak. 3-Substituted oxetanes. The Journal of Organic Chemistry. 1973-06, 38 (11): 2061–2066 [2022-03-22]. ISSN 0022-3263. doi:10.1021/jo00951a020 （英语）.

[2] Randolph A. Escobar, Jeffrey W. Johannes. Reductive Radical Conjugate Addition of Alkyl Electrophiles Catalyzed by a Cobalt/Iridium Photoredox System. Organic Letters. 2021-08-06, 23 (15): 6046–6051 [2022-03-22]. ISSN 1523-7060. doi:10.1021/acs.orglett.1c02114 （英语）.

[3] Andrew R. Bogdan, Neal W. Sach. The Use of Copper Flow Reactor Technology for the Continuous Synthesis of 1,4-Disubstituted 1,2,3-Triazoles. Advanced Synthesis & Catalysis. 2009-04, 351 (6): 849–854 [2022-03-22]. doi:10.1002/adsc.200800758. （原始内容存档于2022-03-22）（英语）.

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