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三甲基氟化锡

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三甲基氟化锡
识别
CAS号 420-60-0  checkY
性质
化学式 C3H9FSn
摩尔质量 182.81 g·mol−1
外观 白色固体
熔点 375 °C[1]
溶解性 难溶[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

三甲基氟化锡是一种有机氟化合物,化学式为(CH3)3SnF。它可由六甲基二锡2,4,6-三硝基氟苯四氢呋喃中加热反应得到,[3]或由三甲基氯化锡乙醇溶液和氟化钾的水溶液反应制得。[4]它可用于将有机基氯化硅转化为相应的氟化物。[5]

参考文献

  1. ^ William Johnson. Notes:The Alkylation of Tin(IV) Chlorides with Alkylaluminums. The Journal of Organic Chemistry. 1960-12, 25 (12): 2253–2254 [2022-03-12]. ISSN 0022-3263. doi:10.1021/jo01082a626. (原始内容存档于2022-03-12) (英语). 
  2. ^ P. M. Treichel, Ruth A. Goodrich. The Reaction of Phosphorus Pentafluoride and Tetraalkyltin Compounds. Inorganic Chemistry. 1965-10, 4 (10): 1424–1428 [2022-03-12]. ISSN 0020-1669. doi:10.1021/ic50032a013 (英语). 
  3. ^ Artamkina, G. A.; Egorov, M. P.; Kharitonov, V. G.; Beletskaya, I. P.; Reutov, O. A. Reaction of picryl halides with hexamethyldistannane. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982. 2: 476-477. ISSN 0002-3353.
  4. ^ Javier Vela, Jeremy M. Smith, Ying Yu, Nicole A. Ketterer, Christine J. Flaschenriem, Rene J. Lachicotte, Patrick L. Holland. Synthesis and Reactivity of Low-Coordinate Iron(II) Fluoride Complexes and Their Use in the Catalytic Hydrodefluorination of Fluorocarbons. Journal of the American Chemical Society. 2005-06-01, 127 (21): 7857–7870 [2022-03-12]. ISSN 0002-7863. doi:10.1021/ja042672l (英语). 
  5. ^ Herbert W. Roesky, Klaus Keller. Trimethyltin fluoride: A new fluorinating reagent for the preparation of silicon fluorides. Journal of Fluorine Chemistry. 1998-04, 89 (1): 3–4 [2022-03-12]. doi:10.1016/S0022-1139(98)00077-3 (英语).