2-丙烯基-4-甲氧基苯酚
Pseudoisoeugenol | |
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IUPAC名 4-Methoxy-2-[(1E)-prop-1-en-1-yl]phenol | |
别名 | 2-(1-Propenyl)-4-methoxyphenol trans-Pseudoisoeugenol |
识别 | |
CAS号 | 17398-03-7 98755-22-7(1E) |
PubChem | 16116489 |
ChemSpider | 17273716 |
SMILES |
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InChI |
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InChIKey | CNTCZYAGRDSWBW-ONEGZZNKSA-N |
性质 | |
化学式 | C10H12O2 |
摩尔质量 | 164.2 g·mol−1 |
密度 | 1.0 g/cm3 |
沸点 | 357.3 °C(630 K) |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
2-丙烯基-4-甲氧基苯酚是天然存在的苯丙烯类化合物,化学式为C10H12O2,它是丁香油酚和异丁香油酚的同分异构体。[1]它可以2-羟基-5-甲氧基苯甲醛为原料反应得到,[2]或通过2-烯丙基-4-甲氧基苯酚的异构化制得。[3]它和烯丙基二甲基氯硅烷在三乙胺存在下反应,可以得到3-丙烯基-4-(烯丙基二甲基硅氧基)苯甲醚。[4]
参考文献
- ^ Reichling, Jürgen; Galati, Enza Maria. Jodral, Manuel Miró , 编. Illicium, Pimpinella and Foeniculum 1st. New York: CRC Press LLC. 2004: 79–90 [2022-03-09]. ISBN 9780203022320. (原始内容存档于2022-03-09).
- ^ Ehu Camille Aka, Eric Wimmer, Elvina Barré, Natarajan Vasudevan, Daniel Cortés-Borda, Tchirioua Ekou, Lynda Ekou, Mireia Rodriguez-Zubiri, François-Xavier Felpin. Reconfigurable Flow Platform for Automated Reagent Screening and Autonomous Optimization for Bioinspired Lignans Synthesis. The Journal of Organic Chemistry. 2019-11-01, 84 (21): 14101–14112 [2022-03-09]. ISSN 0022-3263. doi:10.1021/acs.joc.9b02263. (原始内容存档于2022-02-25) (英语).
- ^ Tuyen Nguyen Van, Silvia Debenedetti, Norbert De Kimpe. Synthesis of coumarins by ring-closing metathesis using Grubbs’ catalyst. Tetrahedron Letters. 2003-05, 44 (22): 4199–4201 [2022-03-09]. doi:10.1016/S0040-4039(03)00902-X. (原始内容存档于2018-06-18) (英语).
- ^ Leticia Jiménez-González, Sergio García-Muñoz, Miriam Álvarez-Corral, Manuel Muñoz-Dorado, Ignacio Rodríguez-García. Silver-Catalyzed Asymmetric Synthesis of 2,3-Dihydrobenzofurans: A New Chiral Synthesis of Pterocarpans. Chemistry - A European Journal. 2006-11-24, 12 (34): 8762–8769 [2022-03-09]. doi:10.1002/chem.200600332 (英语).