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1-十六炔

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1-十六炔
英文名 1-hexadecyne
识别
CAS号 629-74-3
PubChem 12396
SMILES
 
  • C#CCCCCCCCCCCCCCC
InChI
 
  • InChI=1S/C16H30/c1-3-5-7-9-11-13-15-16-14-12-10-8-6-4-2/h1H,4-16H2,2H3
InChIKey UCIDYSLOTJMRAM-UHFFFAOYSA-N
性质
化学式 C16H30
摩尔质量 222.41 g·mol−1
熔点 +15.0
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

1-十六炔是一种有机化合物,化学式C16H30,可见于北美金縷梅[1]鱼腥草[2]羽叶金合欢[3]、辽东栎(Quercus liaotungensis)[4]牛樟[5]等物种。其可在吸附有氢原子的单晶硅(111)晶面上自发吸附形成一层致密的单分子层[6][7]

参考资料

  1. ^ Engel R; Gutmann M; Hartisch C; Kolodziej H; Nahrstedt A. Study on the composition of the volatile fraction of Hamamelis virginiana. Planta Medica. 1998-04, 64 (3). doi:10.1055/S-2006-957420. 
  2. ^ Minmin Liang; Meiling Qi; Changbin Zhang; Shan Zhou; Ruonong Fu; Junxiong Huang. Gas chromatography–mass spectrometry analysis of volatile compounds from Houttuynia cordata Thunb after extraction by solid-phase microextraction, flash evaporation and steam distillation. Analytica Chimica Acta. 2005-02, 531 (1). doi:10.1016/J.ACA.2004.09.082. 
  3. ^ 李贵军,汪帆. 臭菜挥发油化学成分的GC-MS分析. 中国调味品. 2014, (6): 118-120. doi:10.3969/j.issn.1000-9973.2014.06.031. 
  4. ^ 周敬林,王斌赫,王国宝. 2种柞树叶片和树皮中的挥发性化学成分鉴定. 蚕业科学. 2017, 43 (3): 459-466. doi:10.13441/j.cnki.cykx.2017.03.015. 
  5. ^ Cheng, Sen-Sung, Chun-Ya Lin, Chih-Kai Yang, Ying-Ju Chen, Min-Jay Chung, ,Shang-Tzen Chan. Chemical Polymorphism and Composition of Leaf Essential Oils of Cinnamomum kanehirae Using Gas Chromatography/Mass Spectrometry, Cluster Analysis, and Principal Component Analysis. Journal of Wood Chemistry and Technology. 2015, 35 (3): 207-219. doi:10.1080/02773813.2014.924967. 
  6. ^ Luc ScheresMarcel GiesbersHan Zuilhof. Self-Assembly of Organic Monolayers onto Hydrogen-Terminated Silicon: 1-Alkynes Are Better Than 1-Alkenes. Langmuir. 2010, 26 (13): 10924–10929. doi:10.1021/la100858q. 
  7. ^ Bart Rijksen,Sidharam P. Pujari,Luc Scheres,; et al. Hexadecadienyl Monolayers on Hydrogen-Terminated Si(111): Faster Monolayer Formation and Improved Surface Coverage Using the Enyne Moiety. Langmuir. 2012, 28 (16): 6577–6588. doi:10.1021/la204770r.