1,3-二乙烯基苯

1,3-二乙烯基苯
识别
CAS号	108-57-6
性质
化学式	C10H10
摩尔质量	130.19 g·mol−1
熔点	−52.3 °C（220.8 K）
沸点	121 °C（394 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

1,3-二乙烯基苯是一种有机化合物，化学式为C₁₀H₁₀。它可由1,3-二碘苯和四乙烯基硅在钯催化下反应得到。^[2]1,3-苯二甲醛和三苯基甲基溴化𬭸在叔丁醇钾的存在下反应，也能得到1,3-二乙烯基苯。^[3]它和溴反应，根据反应条件不同，可以得到1,5-二溴-2,4-二乙烯基苯^[4]或1,3-二(1,2-二溴乙基)苯^[5]。它和苯甲酰胺、氢氧化钾在二甲基亚砜中于120 °C反应，可以得到N,N'-(1,3-苯二亚基-2,1-乙二基)二苯甲酰胺。^[6]

参考文献

^ ^1.0 ^1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-06-30].
^ Abdessamad Grirrane, Hermenegildo Garcia, Avelino Corma. Supported palladium nanoparticles as heterogeneous ligand-free catalysts for the Hiyama C–C coupling of vinylsilanes and halobenzenes leading to styrenes. Journal of Catalysis. 2013-06, 302: 49–57 [2021-06-30]. doi:10.1016/j.jcat.2013.02.019. （原始内容存档于2018-06-11）（英语）.
^ Shunsuke Tanaka, Masayoshi Matsumoto, Raita Goseki, Takashi Ishizone, Akira Hirao. Living Anionic Polymerization of 1,4-Divinylbenzene and Its Isomers. Macromolecules. 2013-01-08, 46 (1): 146–154 [2021-06-30]. ISSN 0024-9297. doi:10.1021/ma302246u （英语）.
^ Cui, Aijun; Tian, Junkai; Liu, Liu; Li, Jing; Chen, Qun; He, Mingyang. Preparation of 1,3-divinyl-4,6-benzenedicarboxylic acid oxygen absorbents for oxygen-absorbing polyester. 2012. CN 102746496 A.
^ Mitchell, Reginald H.; Ghose, Bhupendra N.; Williams, Mary E. The intra- and intermolecular copper (I) catalyzed couplings of vinyl Grignards. A facile synthesis of pleiadiene and a synthesis of a conjugated 14-membered ring system. Canadian Journal of Chemistry. 1977, 55 (2): 210–219. ISSN 0008-4042. doi:10.1139/v77-035.
^ Ayushee, Monika Patel, Priyanka Meena, Kousar Jahan, Prasad V. Bharatam, Akhilesh K. Verma. Base-Mediated Anti-Markovnikov Hydroamidation of Vinyl Arenes with Arylamides. Organic Letters. 2021-01-15, 23 (2): 565–570 [2021-06-30]. ISSN 1523-7060. doi:10.1021/acs.orglett.0c04084 （英语）.

[data-1] 1.0 ^1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-06-30].

[2] Abdessamad Grirrane, Hermenegildo Garcia, Avelino Corma. Supported palladium nanoparticles as heterogeneous ligand-free catalysts for the Hiyama C–C coupling of vinylsilanes and halobenzenes leading to styrenes. Journal of Catalysis. 2013-06, 302: 49–57 [2021-06-30]. doi:10.1016/j.jcat.2013.02.019. （原始内容存档于2018-06-11）（英语）.

[3] Shunsuke Tanaka, Masayoshi Matsumoto, Raita Goseki, Takashi Ishizone, Akira Hirao. Living Anionic Polymerization of 1,4-Divinylbenzene and Its Isomers. Macromolecules. 2013-01-08, 46 (1): 146–154 [2021-06-30]. ISSN 0024-9297. doi:10.1021/ma302246u （英语）.

[4] Cui, Aijun; Tian, Junkai; Liu, Liu; Li, Jing; Chen, Qun; He, Mingyang. Preparation of 1,3-divinyl-4,6-benzenedicarboxylic acid oxygen absorbents for oxygen-absorbing polyester. 2012. CN 102746496 A.

[5] Mitchell, Reginald H.; Ghose, Bhupendra N.; Williams, Mary E. The intra- and intermolecular copper (I) catalyzed couplings of vinyl Grignards. A facile synthesis of pleiadiene and a synthesis of a conjugated 14-membered ring system. Canadian Journal of Chemistry. 1977, 55 (2): 210–219. ISSN 0008-4042. doi:10.1139/v77-035.

[6] Ayushee, Monika Patel, Priyanka Meena, Kousar Jahan, Prasad V. Bharatam, Akhilesh K. Verma. Base-Mediated Anti-Markovnikov Hydroamidation of Vinyl Arenes with Arylamides. Organic Letters. 2021-01-15, 23 (2): 565–570 [2021-06-30]. ISSN 1523-7060. doi:10.1021/acs.orglett.0c04084 （英语）.

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