四己基溴化铵
| 四己基溴化铵 | |
|---|---|
| 识别 | |
| CAS号 | 4328-13-6 
|
| 性质 | |
| 化学式 | C24H52BrN |
| 摩尔质量 | 434.58 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
四己基溴化铵是一种季铵盐，化学式为[CH3(CH2)5]4NBr，它可用作相转移催化剂。[1]
反应
它在碳酸钾存在下和苯并三唑反应，可以得到1-己基苯并三唑。[2]
它和高锰酸钾在水中反应，可以得到紫色的四辛基高锰酸铵沉淀。[3]
参考文献
- ^ Dario Landini; Angelamaria Maia; Alessandro Rampoldi. Stability of quaternary onium salts under phase-transfer conditions in the presence of aqueous alkaline solutions. J. Org. Chem. 1986, 51, 16, 3187–3191. doi:10.1021/jo00366a022.
- ^ Khalafi-Nezhad, A.; et al. Quaternary ammonium salts as highly efficient and green alkylating agents for N-alkylation of azaheterocycles under microwave irradiation. Journal of the Iranian Chemical Society (2008), 5. S40-S46. doi:10.1007/BF03246487
- ^ Boskovic, Colette; et al. Tetranuclear manganese carboxylate clusters with imidazole-carboxylate chelating ligands. X-ray crystal structure of the 4-imidazoleacetate complex. Polyhedron (2000), 19(18-19), 2111-2118. doi:10.1016/S0277-5387(00)00516-7.