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吡啶-4-乙腈

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吡啶-4-乙腈
识别
CAS号 13121-99-8  checkY
SMILES
 
  • N#CCC=1C=CN=CC1
性质
化学式 C7H6N2
摩尔质量 118.14 g·mol−1
熔点 36 °C[1]
沸点 92 °C(0.5 mmHg)[1]
溶解性 2.7 g/100 mL(25 °C)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

吡啶-4-乙腈是一种有机化合物,化学式为C7H6N2。它存在市售品,实验室可直接购得使用。[3]它也可以4-氯吡啶盐酸盐和氰乙酸乙酯为原料反应制得。[4]

反应

它和碘甲烷反应,可以得到N-甲基-4-氰甲基吡啶鎓碘化物。[5]

参考文献

  1. ^ 1.0 1.1 B. E. Betts and W. Davey. Cyclohexane-1,3-diones. Part VI. Structural requirements for the displacement of the alkoxyl by the cyano-group in the enol ethers of cyclic β-diketones. J. Chem. Soc., 1961, 3333-3340. doi:10.1039/JR9610003333.
  2. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software (© 1994-2024 ACD/Labs). Retrieved from SciFinder. [2024-11-06].
  3. ^ Shimin Zhou; Qing Lu; Yanan Sun; Zhiqiang Liu; Xiaoqiang Yu. Synthesis, structure, and aggregated state emission of regio-isomeric 3-Pyrenyl-2-(4′-Pyridinyl)-Acrylonitrile. Journal of Photochemistry and Photobiology A: Chemistry, 2020. 389. 112212. doi:10.1016/j.jphotochem.2019.112212.
  4. ^ 宋吾燕; 赵春深; 宋朝友; 孟仁勇. 2-(吡啶-4-基)乙腈的合成. 广东化工, 2014. 41 (6): 12.
  5. ^ Jiang, Huimin; Yin, Guoxing; Gan, Yabing; Yu, Ting; Zhang, Youyu; Li, Haitao; Yin, Peng. A multisite-binding fluorescent probe for simultaneous monitoring of mitochondrial homocysteine, cysteine and glutathione in live cells and zebrafish. Chinese Chemical Letters (2022), 33(3), 1609-1612. doi:10.1016/j.cclet.2021.09.036.