五氯合铟酸铯

五氯合铟酸铯
识别
CAS号	23254-32-2（无水） ; 29934-45-0（一水）
性质
化学式	Cl5Cs2In
摩尔质量	557.89 g·mol−1
外观	晶体
密度	3.447 g·cm−1（一水）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

五氯合铟酸铯是一种无机化合物，化学式为Cs₂InCl₅，它存在无水物和一水合物Cs₂[InCl₅(H₂O)]。无水物为不一致（incongruently）熔体，包晶温度428 °C^[1]，InCl₅²⁻具有四面体和八面体结构（对比溴代类似物由溴桥连接）。^[2]它的一水合物可由氯化铟和氯化铯在盐酸中加热反应，再降温结晶得到，^[3]其中的[InCl₅(H₂O)]²⁻为八面体构型。^[4]

参考文献

^ Sryvtsev, V. A.; Arbekov, V. N.; Petrov, E. S. Composition-temperature diagrams of MCl3-RbCl and MCl3-CsCl(M = Ga, In) systems. Redk. Shchelochnye Elem., Sb. Dokl. Vses. Soveshch., 2nd, Novosibirsk. 1967. pp 191-199. CODEN 20BYA9.
^ Bogatov, Yu. E.; Mazo, G. Ya.; Molodkin, A. K.; Dudareva, A. G. Study of complexes formed in InH₃-MH systems (where H = chloride, bromide, iodide and M = lithium, sodium, potassium, rubidium, cesium) by IR-spectroscopic methods. Zhurnal Neorganicheskoi Khimii, 1978. 23 (4): 935-942. ISSN 0044-457X.
^ Jun-Hua Wei, Jian-Bin Luo, Jin-Feng Liao, Wei-Tao Ou, Dai-Bin Kuang. Te4+-doped Cs2InCl5·H2O single crystals for remote optical thermometry. Science China Materials. 2022-03, 65 (3): 764–772 [2022-05-25]. ISSN 2095-8226. doi:10.1007/s40843-021-1792-1 （英语）.
^ X. Solans, M. C. Moron, F. Palacio. Structures of Rb 2 [InCl 5 (H 2 O)] and Cs 2 [InCl 5 (H 2 O)]. Acta Crystallographica Section C Crystal Structure Communications. 1988-06-15, 44 (6): 965–967 [2022-05-25]. ISSN 0108-2701. doi:10.1107/S0108270188001349. （原始内容存档于2022-05-25）.

[1] Sryvtsev, V. A.; Arbekov, V. N.; Petrov, E. S. Composition-temperature diagrams of MCl3-RbCl and MCl3-CsCl(M = Ga, In) systems. Redk. Shchelochnye Elem., Sb. Dokl. Vses. Soveshch., 2nd, Novosibirsk. 1967. pp 191-199. CODEN 20BYA9.

[2] Bogatov, Yu. E.; Mazo, G. Ya.; Molodkin, A. K.; Dudareva, A. G. Study of complexes formed in InH₃-MH systems (where H = chloride, bromide, iodide and M = lithium, sodium, potassium, rubidium, cesium) by IR-spectroscopic methods. Zhurnal Neorganicheskoi Khimii, 1978. 23 (4): 935-942. ISSN 0044-457X.

[3] Jun-Hua Wei, Jian-Bin Luo, Jin-Feng Liao, Wei-Tao Ou, Dai-Bin Kuang. Te4+-doped Cs2InCl5·H2O single crystals for remote optical thermometry. Science China Materials. 2022-03, 65 (3): 764–772 [2022-05-25]. ISSN 2095-8226. doi:10.1007/s40843-021-1792-1 （英语）.

[4] X. Solans, M. C. Moron, F. Palacio. Structures of Rb 2 [InCl 5 (H 2 O)] and Cs 2 [InCl 5 (H 2 O)]. Acta Crystallographica Section C Crystal Structure Communications. 1988-06-15, 44 (6): 965–967 [2022-05-25]. ISSN 0108-2701. doi:10.1107/S0108270188001349. （原始内容存档于2022-05-25）.

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