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5-癸酮

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5-癸酮
英文名 5-decanone
识别
CAS号 820-29-1  checkY
PubChem 13175
SMILES
 
  • CCCCCC(=O)CCCC
InChI
 
  • InChI=1S/C10H20O/c1-3-5-7-9-10(11)8-6-4-2/h3-9H2,1-2H3
InChIKey JDPQWHLMBJZURR-UHFFFAOYSA-N
性质
化学式 C10H20
摩尔质量 140.27 g·mol−1
沸点 84—86 °C（357—359 K）（8 mmHg）[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

5-癸酮（英語：5-decanone）是一种有机化合物，化学式C10H20O，可见于石榴[2]等物种。它可由5-癸醇（德语：5-Decanol）在催化下氧化制得[3]，或由己酰氯（英语：Hexanoyl chloride）和正丁基氯化镁（德语：Butylmagnesiumchlorid）（或正丁基锂[4]）反应得到。[5]

参考资料

  1. ^ G. Forrest Woods; Henry F. Lederle. The Chemistry of Pentadienal and its Derivatives. J. Am. Chem. Soc. 1951, 73, 5, 2245–2247. doi:10.1021/ja01149a093.
  2. ^ A.M.M. Costa; L.O. Silva. Chemical composition of commercial cold-pressed pomegranate (Punica granatum) seed oil from Turkey and Israel, and the use of bioactive compounds for samples’ origin preliminary discrimination. Journal of Food Composition and Analysis. 2018-09, 75. doi:10.1016/J.JFCA.2018.09.004. 
  3. ^ Park, Kwihwan; Jiang, Jing; Yamada, Tsuyoshi; Sajiki, Hironao. Ruthenium-on-carbon-catalyzed facile solvent-free oxidation of alcohols: efficient progress under solid-solid (liquid)-gas conditions. Source Chemical & Pharmaceutical Bulletin, 2021. 69 (12): 1200-1205. doi:10.1248/cpb.c21-00749.
  4. ^ Jae Kyo Park , Won Kyu Shin , Duk Keun An. An effective one-pot conversion of acid chlorides to aldehydes and ketones. Tetrahedron Letters, 2013. 54 (24): 3199-3203. doi:10.1016/j.tetlet.2013.04.041.
  5. ^ Maria Michela Dell'Anna; Piero Mastrorilli, Cosimo F Nobile, Giuseppe Marchese, Maria Rosaria Taurino. Coupling reactions between acyl chlorides and Grignard reagents in the presence of a supported Fe(III)-complex. Journal of Molecular Catalysis A: Chemical, 2000. 161 (1-2): 239-243. doi:10.1016/S1381-1169(00)00268-5.
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